Actually, LE isn't even necessary. I found this article on Logic Remote which acts as a sort of companion iPad app for Logic Pro, and was able to use the steps in it to control Alfred on my Mac from my iPad with WiFi off:
http://support.apple.com/en-us/HT202765
This apparently sets up a Bluetooth personal area network where both devices get self-assigned IPs in the same subnet and mDNS works as usual for service discovery. I'm using Yosemite and iOS 8 so I don't know how far back this works but as of the current OS releases it seems to work 'out of the box' already.