Just to ensure I'm using it correctly, when I have a page open in Chrome, I open Alfred & type URL which should then look as your screenshot does?
When I open Alfred and type URL, the URL is not listed as in your screenshot. Also, the workflow automatically launches Safari which is not running. The URL is not copied no matter what option is chosen. Ideas?
Also, If I choose send to Safari, it jumps to the workflow folder in Finder. Send to Chrome opens an index of the workflow folder.